Looking at the second link...
I'd imagine the spillover rate from China is really messing Japan up. I thought Japan had better industry standards than the U.S. when it came to air pollution but it might just be that the larger land size reduces the average ppm for the U.S., and its really much higher than Japan.
NJ no surprise there. A drive on the parkway or turnpike should be plenty of evidence.
Also, why is the ppm so high for the Congo? Burning of forests?
For the U.S., agriculture produces a crap (methane) load of it.